Monkey D. Luffy underwent training for 2 years under the tutelage of Gol D. Roger's right hand, Silver Rayleigh. The reason Rayleigh wanted to train Luffy was because he saw the similarities between Luffy and Roger. Besides Luffy, here are some other characters who might also be suitable to be trained by Rayleigh!

1. Kin’emon

As the leader of the Akazaya Nine who protects the Kozuki clan, Kin'emon must become stronger than he is now so that one day he can face an opponent as strong as Kaido without the help of Luffy and the others.

That's why he is one of the suitable people to be trained by Silver Rayleigh. If he is able to master all three types of Haki, Kin'emon will look more suitable to lead Akazaya Nine.

2. Usopp

As a legendary pirate who is also the closest person to the Pirate King, Rayleigh is very good at all three types of Haki. What Usopp really needed as a sniper is the insane mastery of Kenbunshoku Haki.

That's the reason for him to be trained by someone as strong as Rayleigh. If Rayleigh trained Usopp at that time, he might be as strong as Yasopp or Van Augur today.

3. Roronoa Zoro

If at that time Zoro was not trained by Mihawk, Rayleigh could also replace the role of the strongest swordsman in the world. Rayleigh is also a swordsman so he should know better what Zoro needs.

If Zoro were studied Rayleigh, his fighting techniques may not be as varied as they are today. It's likely that his Haoshoku Haki will be stronger than the captain, Luffy.

4. Mr. 2

At the beginning of the story, Mr. 2 was indeed the opponent of the Straw Hat crew. But after the Arabasta arc, he became Luffy's best friend who saved his life several times. He even sacrificed his own life by fighting Magellan for Luffy who he considered a good friend.

With Okama Kempo self-defense, Mr. 2 will be much stronger if he mastered all three types of Haki. Therefore, Rayleigh could also be a suitable mentor for him.

5. Marco

Marco is already strong from the start. He is also the former commander of the Whitebeard Pirates' first division, but Rayleigh was still stronger than him. This is seen in flashbacks of the war between the Roger Pirates and Whitebeard. Rayleigh could stop Marco's attack with just one finger.

Given that ability, perhaps Marco needs to learn from Rayleigh to maximize his fighting power and using Haki at master level.

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6. Sabo

Sabo is Luffy's adopted brother besides Ace who now posesses the Mera Mera no Mi. Sabo really cares for Luffy and will help him whenever he needs. Sabo is also the number 2 person in the Revolutionary Army after Dragon.

He had indeed been trained by Dragon and possessed powerful Haki. As Luffy's brother, Rayleigh definitely supports Sabo and is willing to teach him the use of Haki or other techniques that he may not have mastered.

7. Trafalgar Law

Law has been very strong since the Wano arc. There are many new techniques that he has shown since his fight against Doflamingo in Dressrosa, but Law's potential can still develop further.

As one of the people with the name D, Law is most likely also able to master Haoshoku Haki. This is why Rayleigh is the right person to help Law awaken that ability.

8. Portgas D. Ace

Rayleigh had never met Ace. If Ace was still alive, he would have greatly respected Rayleigh as Luffy's teacher and also Shanks' partner when he was still in Roger's crew.

Ace grew strong without being trained by anyone. He only had a lot of experience in the wild as a child with Sabo and Luffy. Ace might need someone who can train him to master even higher Haki.

9. Buggy

Buggy is a former Rayleigh's shipmate when he was still sailing in Roger's group. At that time, he was still a kid. Buggy had great respect for Rayleigh as vice-captain. He also doesn't want to disappoint Rayleigh even though he had tried to escape from the ship with the Bara Bara no Mi.

It's likely that Buggy was trained by Rayleigh after the Roger Pirates were disbanded. Buggy needs Rayleigh to unlock his Haki potential, as well as the new Bara Bara no Mi technique which can be very powerful.

10. Shanks

Apart from Buggy, Shanks is someone who has great respect for Rayleigh in Roger's group. At that time, the difference in their abilities is still very far. The most suitable person to train little Shanks at that time was Rayleigh.

Come to think of it, it made sense that Rayleigh would train him so that Shanks could become as strong as he is today and even become a Yonkou.

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